Perhaps the empty d-orbitals on P has a similar energy (effective orbital overlap) with the metal d-orbitals and so can accept electron density, whereas N with a lower nuclear attraction and highly energetic 3d orbitals cannot achieve effective orbital overlap to accept electron density.
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Perhaps the empty d-orbitals on P has a similar energy (effective orbital overlap) with the metal d-orbitals and so can accept electron density, whereas N with a lower nuclear attraction and highly energetic 3d orbitals cannot achieve effective orbital overlap to accept electron density.
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